Analytical Sciences

Core-shell Au@Pt Nanoparticles Catalyzed Luminol Chemiluminescence for Sensitive Detection of Thiocyanate

Ze WANG,* Bin DONG,* Xiaoqian CUI,** Qian FAN,*** Yanfu HUAN,* Hongyan SHAN,* Guodong FENG,* and Qiang FEI*

*Department of Analytical Chemistry, College of Chemistry, Jilin University, Jiefang 2519, Changchun 130012, P. R. China
**Department of Emergency and Critical Care, the Second Hospital of Jilin University, Changchun 130041, P. R. China
***Changchun Polytechnic, Changchun 130033, P. R. China

In this study, core-shell Au@Pt nanoparticles (Au@Pt NPs) with peroxidase catalytic activity were synthesized by the seed-mediated method, and were used to catalyze the reaction of luminol–H₂O₂ to enhance the chemiluminescence (CL) intensity. It was found that thiocyanate (SCN⁻) can effectively inhibit the catalytic activity of Au@Pt NPs. Based on this phenomenon, a method to detect SCN⁻ by using the Au@Pt NPs-catalytic luminol–H₂O₂ CL system was established, which has an ultra-low detection limit and an ultra-wide linear range, as well as the advantages of being simple and having low-cost and convenient operation. The research mechanism indicated that SCN⁻ could be adsorbed on the surface of Au@Pt NPs and occupies the active sites of Pt nanostructures, which led to a decrease in the amount of Pt⁰ and a loss of the excellent catalytic activity of Au@Pt NPs. After optimizing the experimental conditions, this assay for detecting SCN⁻ exhibited a good linear range from 5 to 180 nM, and the low detection limit was 2.9 nM. In addition, this approach has been successfully applied to the detection of SCN⁻ in tap-water samples, which has practical application value and embodies good development prospects.

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