Analytical Sciences

Abstract − Analytical Sciences, 36(8), 953 (2020).

A Performance-enhanced Electroosmotic Pump with Track-etched Polycarbonate Membrane by Allylhydridopolycarbosilane Coating
Shumei TIAN, Wenli ZHANG, Jinwei SHI, Zixian GUO, and Ming LI
Jiangsu Key Laboratory of Environmental Material and Environmental Engineering, College of Environmental Science and Engineering, Yangzhou University, Yangzhou 225127, China
Nanochannel plastic membranes are excellent materials for electroosmotic pump (EOP) elements owing to their surface charge properties, flexibility and cost-effectiveness. However, the surface charge properties of plastics are inferior to those of silicate-based materials. This paper reports a performance-enhanced EOP equipped with a glassified track-etch polycarbonate membrane (PC), which has a nanochannel surface covered by allylhydridopolycarbosilane (AHPCS). The effects of applied voltage, pH and membrane pore size on the electroosmotic flow velocity, along with a comparative study of the EOP with coated and pure membranes were investigated. It was found that when low DC voltage (10 – 40 V) was applied to both ends of the pump, the magnitude of the electroosmotic flow was linearly proportional to the voltage when the pore size of the membrane was less than 600 nm. A higher flow rate was obtained with larger pore size membranes. Compared with the uncoated film, the coated one showed faster electroosmosis velocity, with higher stability under the same conditions. For pH 10.0 buffer solution, a flow rate of 89.13 μL/min was obtained in the modified membrane-based EOP with excellent repeatability and durability, while the flow rate was only 37.89 μL/min in the bare PC membrane under 20 V. In order to demonstrate the performance of the developed EOP, the EOP was used for microcomplexometric titration to determine actual tap water hardness. The measured results were highly consistent with the results of a conventional complexometric titration methed. The EOP with an AHPCS-coated plastic membrane expanded the application range to harsh condition solutions, such as high-concentration acids or bases.