Analytical Sciences

A Heterocyclic-based Bifunctional Sensor for Detecting Cobalt and Zinc Ion

Haeri SO, Hangyul LEE, and Cheal KIM

Department of Fine Chemistry, Seoul National University of Science and Technology, Seoul 01178, Korea

A new bifunctional chemosensor HBP ((E)-2-(2-((5-bromopyridin-2-yl)methylene)hydrazinyl) quinoline) based on heterocyclic compounds was designed and studied. The HBP showed successful detecting ability toward cobalt ion with a UV-visible red-shift and a color change of colorless to pink. Moreover, toward zinc ion, the HBP showed an obvious fluorescence turn-on response. The binding ratio of the HBP to cobalt and zinc was a 2 to 1 for both ions. The detection limits were found to be 10 nM for Co²⁺ and 18 nM for Zn²⁺. Based on UV-vis and fluorescent spectral variations, Job plots, ESI-MS, FT-IR and calculations, the binding mechanisms of the HBP toward cobalt and zinc ions were proposed.

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