Analytical Sciences

Determination of Eleven Organophosphorus Pesticide Residues in Textiles by Using HPLC-HRMS

Ting-Ting HU,*1,*2 Chun-Mei LU,*2 Han LI,*1,*3 Zai-Xiao ZHANG,*4 Yun-Hui ZHAO,*2 and Juan LI*1

*1 School of Public Health, Jilin University, Changchun 130021, P. R. China
*2 Department of Technical Center, Jilin Entry Exit Inspection and Quarantine Bureau, Changchun 130062, P. R. China
*3 Department of Nosocomial Infection Management, The First Hospital of Jilin University, Changchun 130021, P. R. China
*4 College of Life Sciences, Jilin University, Changchun 130012, P. R. China

The overuse of organophosphorus pesticides on cotton production is a big concern in China today. Therefore, developing methods for the rapid screening and confirming of pesticide residues in textiles has become a top public health security priority. Here, a method was established for the rapid screening and quantifying of 11 kinds of organophosphorus pesticides (ethoprophos, coumaphos, profenofos, diazinon, ethion, parathion, phosalone, quinalphos, dicrotophos, azinphos methyl, and tribuphos) in textiles by high-performance liquid chromatography high-resolution mass spectrometry (HPLC-HRMS). Rapid screening and quantifying could be completed by using software of Peakview and MultiQuant. Samples were extracted by the method of modified QuEChERS (Quick, Easy, Cheap, Effective, Rugged and Safe) and analyzed in the positive mode with MS detection. The results showed that the limits of detection were between 0.1 and 5.0 ng g⁻¹, with correlation coefficients above 0.9990. The recoveries were in the range of 70.3 – 109.8%, with relative standard deviations from 5.1 to 16.4%. This method is accurate and simple, which can be used in the rapid screening and quantitative analysis of 11 kinds of organophosphorus pesticides in textiles.

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