Analytical Sciences

Electrochemical Determination of Bisphenol A with Pencil Graphite Electrodes Modified with Co(II), Ni(II), Cu(II) and Fe(II) Phthalocyaninetetrasulfonates

Levent ÖZCAN,* Muhammet ALTUNTAS,** Aysel BÜYÜKSAGIS,** Hayrettin TÜRK,*** and Sedat YURDAKAL**

*Biyomedikal Mühendisligi Bölümü, Mühendislik Fakültesi, Afyon Kocatepe Üniversitesi, Ahmet Necdet Sezer Kampüsü, 03200, Afyonkarahisar, Turkey
**Kimya Bölümü, Fen-Edebiyat Fakültesi, Afyon Kocatepe Üniversitesi, Ahmet Necdet Sezer Kampüsü, 03200, Afyonkarahisar, Turkey
***Kimya Bölümü, Fen Fakültesi, Anadolu Üniversitesi, Yunus Emre Kampüsü, 26470, Eskisehir, Turkey

Pencil graphite electrodes modified with Co(II), Ni(II), Cu(II) and Fe(II) metallophthalocyaninetetrasulfonates (MePcTSs) were investigated for an electrochemical determination of bisphenol A (BPA). The electrochemical performances of the modified electrodes for different pH values in phosphate and the Britton–Robinson buffers were determined by cyclic voltammetry; the electrode performances were better in the Britton–Robinson buffer. NiPcTS and CoPcTS modifications of the electrodes had remarkable enhancements on their performances. The differential pulse voltammetry parameters for the electrodes were optimized, and we found that the electrochemical response versus the concentration of BPA is linear from 5.0 × 10⁻⁷ to 1.0 × 10⁻⁵ M for the NiPcTS and CoPcTS modified electrodes. The detection limits of these modified electrodes are 2.9 × 10⁻⁷ and 4.3 × 10⁻⁷ M, respectively, and the effects of interfering species are less than 5%. The results show that NiPcTS and CoPcTS modified pencil graphite electrodes could be used for electrochemical determinations of BPA for analytical purposes.

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