Analytical Sciences

Preparation of a Magnetic Metal Organic Framework Composite and Its Application for the Detection of Methyl Parathion

LiPing HU,* Nan WU,* Jing ZHENG,* JingLi XU,* Min ZHANG,* and PinGang HE**

*College of Chemistry and Chemical Engineering, Shanghai University of Engineering Science, Shanghai 201620, P. R. China
**Department of Chemistry, East China Normal University, Shanghai 200062, P. R. China

A magnetic metal organic framework (MOF) composite was prepared. The composite was fabricated by incorporation of Fe₃O₄ nanoparticals with MOF. It was characterized and expected to offer a promising template for molecular immobilization and sensor fabrication because of its ordered structure and satisfying large specific surface area. The resulting composite was used to detect methyl parathion. Electrochemical measurements showed that the multifunctional composite of MOF provided an excellent matrix for the co-adsorption of methyl parathion. Owing to the ordered structure, the large surface area, excellent compatibility and magnetic property of the material, methyl parathion could be separated, accumulated and directly detected in the solution with high sensitivity. The differential pulse voltammetry (DPV) response was proportional to the concentration range from 5.00 × 10⁻⁶ to 5.00 × 10⁻³ g L⁻¹ with the detection limit of 3.02 × 10⁻⁶ g L⁻¹. The experimental results can lead to a widespread use of electrochemical sensors to detect organophosphorous pesticides contaminates and other substances.

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