Analytical Sciences

Abstract − Analytical Sciences, 25(6), 789 (2009).

Potentiometric Detection of Mercury(II) Ions Using a Carbon Paste Electrode Modified with Substituted Thiourea-Functionalized Highly Ordered Nanoporous Silica
Mehran JAVANBAKHT,*1,*2 Faten DIVSAR,*3 Alireza BADIEI,*4 Mohammad Reza GANJALI,*5 Parviz NOROUZI,*5 Ghodsi MOHAMMADI ZIARANI,*6 Marzieh CHALOOSI,*3 and Ali ABDI JAHANGIR*4
*1 Department of Chemistry, Amirkabir University of Technology, Tehran, Iran
*2 Nano Science and Technology Research Center, Amirkabir University of Technology, Tehran, Iran
*3 Faculty of Chemistry, Tarbiat Moalem University, Tehran, Iran
*4 School of Chemistry, University College of Science, University of Tehran, Tehran, Iran
*5 Center of Excellence in Electrochemistry, Faculty of Chemistry, University of Tehran, Tehran, Iran
*6 Department of Chemistry, Faculty of Science, Alzahra University, Iran
A potentiometric sensor is reported for the mercury(II) detection, which uses substituted thiourea-functionalized nanoporous silica (FTU-LUS-1) as the sensitive material. Substituted thiourea (FTU) and FTU-LUS-1 were first prepared and then characterized by 1H NMR, 19F NMR, 13C NMR, FTIR, XRD, TG and CNS elemental analysis. The electrodes with FTU-LUS-1 proportion of 10.0 wt% demonstrated very stable potentials. The prepared electrodes exhibit a Nernstian slope of 28.4 ± 1.0 mV decade−1 for mercury(II) ion over a wide concentration range of 1.0 × 10−7 to 1.0 × 10−1 mol dm−3. The electrode exhibited a detection limit of 7.0 × 10−8 mol dm−3. Moreover, the selectivity coefficient, response time, performance, sensitivity and stability of the modified electrode were investigated. The electrode presented a response time of about 35 s, a high performance and sensitivity in a wide range of cation activities as well as good long term stability (more than 9 months). The method was satisfactory and could also be used to monitor the mercury(II) ion concentration in waste water and fish samples.