Analytical Sciences

Gas Chromatography-Optical Fiber Detector for the Speciation of Aromatic Hydrocarbons in Confined Areas

Lurdes I. B. SILVA,*^,** Teresa A. P. ROCHA-SANTOS,* and A. C. DUARTE**

*ISEIT/VISEU-Instituto Piaget, Estrada do Alto do Gaio, Galifonge, 3515-776 Lordosa, Viseu, Portugal
**CESAM & Department of Chemistry, University of Aveiro, 3810-193 Aveiro, Portugal

An analytical method, based on separation with gas chromatography (GC) and detection with optical fiber (OF), was used for the separation, detection and quantification of benzene, toluene, ethylbenzene, p-xylene, m-xylene and o-xylene. The use of OF as a detector is based on the variations of the reflected optical power detected when the aromatic compounds eluted from the GC column are sorbed in a thin polymeric film on a single-mode OF. General figures of merit, such as the analytical time, analytical error and analytical performance of GC-OF were similar to those of the classical analytical methods, such as a gas chromatography-flame ionization detector (GC-FID). However, the developed GC-OF method constitutes a much less expensive alternative for the speciation of aromatic hydrocarbons compounds, with high accuracy, and being most suitable for actual monitoring work on confined environments.

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