Analytical Sciences

Electrochemical Behavior of Ascorbic Acid at a 2,2′-[3,6-Dioxa-1,8-octanediylbis(nitriloethylidyne)]-bis-hydroquinone Carbon Paste Electrode

Zahra TALEAT,* Mohammad MAZLOUM ARDAKANI,* Hossein NAEIMI,** Hadi BEITOLLAHI,* Maryam NEJATI,** and Hamid REZA ZARE*

*Department of Chemistry, Faculty of Science, Yazd University, Yazd, Iran
**Department of Chemistry, Faculty of Science, Kashan University, Kashan, Iran

Electrocatalytic oxidation of ascorbic acid (AA) at a carbon paste electrode, chemically modified 2,2′-[3,6-dioxa-1,8-octanediylbis(nitriloethylidyne)]-bis-hydroquinone, was thoroughly investigated. The results of cyclic voltammetry, double potential-step chronoamperometry, linear sweep voltammetry and differential pulse voltammetry (DPV) studies were used for the prediction of the mechanism of electrochemical oxidation of AA mediated with 2,2′-[3,6-dioxa-1,8-octanediylbis(nitriloethylidyne)]-bis-hydroquinone at the surface of the modified electrode. The diffusion coefficient (D = 2.45 × 10^-5 cm² s^-1) and the kinetic parameters such as the electron transfer coefficient (α = 0.34) were also determined. The results of DPV using the 2,2′-[3,6-dioxa-1,8-octanediylbis(nitriloethylidyne)]-bis-hydroquinone-modified electrode were applied in a highly sensitive determination of AA in drug samples. A linear range of 3.0 × 10^-6 1.2 × 10^-4 M and the detection limit (3σ) 3.8 × 10^-7 M were obtained for DPV determination of AA in buffered pH 7.00 solutions (0.1 M phosphate buffer).

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