Analytical Sciences

Determination of Mercury in Fish Tissue Using a Minianalyzer Based on Cold Vapor Atomic Absorption Spectrometry at the 184.9 nm Line

Maria-Cristina RIZEA,* Maria-Cristina BRATU,** Andrei Florin DANET,* and Adrian BRATU***

*Faculty of Chemistry, University of Bucharest, Sos. Panduri, No. 90-92, 050663 Bucharest, Romania
**Medicine Preventive Center, M. Ap. N., Str. M. Vulcanescu, No. 88, 010825 Bucharest, Romania
***Top Analitic S. R. L., Dealul Macinului Street, No. 10, 062047 Bucharest, Romania

A sensitive method was proposed and optimized for the determination of total mercury in fish tissue by using wet digestion, followed by cold vapor atomic absorption spectrometry (CVAAS) at the main resonance line of mercury (184.9 nm). The measurements were made using a new type of a non-dispersive mercury minianalyzer. This instrument was initially designed and built for atmospheric mercury-vapor detection. For determining mercury in aqueous samples, the minianalyzer was linked with a mercury/hydride system, Perkin Elmer Model MHS-10. To check the method, the analyzed samples were spiked with a standard solution of mercury. The recoveries of mercury spiked to wet fish tissue were >90% for 0.5 - 0.8 g samples. The results showed a better sensitivity (about 2.5 times higher) when using the mercury absorption line at 184.9 nm compared with the sensitivity obtained by conventional CVAAS at 253.7 nm.

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