Analytical Sciences

Sulfate-selective Electrode Based on a Complex of Copper

M. MAZLOUM ARDAKANI,* Z. AKRAMI,* M. MANSOURNIA,** and Hamid R. ZARE*

*Chemistry Department, Yazd University, Yazd, Iran
**Chemistry Department, Kashan University, Kashan, Iran

A new sulfate-selective electrode based on the complex N,N′-bis(2-amino-1-oxo-phenelenyl)phenylenediamine copper(II) (CuL) as the membrane carrier was developed. The electrode exhibited a good Nernstian slope of -29.5 ± 0.5 mV/decade and a linear range of 1.0 × 10^-7 - 1.0 × 10^-1 M for sulfate. The limit of detection was 1.0 × 10^-8 M. It has a fast response time of 10 s and can be used for more than three months. The selective coefficients were determined by the fixed interference method (FIM). The electrode could be used in the pH range 3.5 - 8.0. It was employed as an indicator electrode for direct determination of sulfate in pharmacy and cement samples.

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