Analytical Sciences

Evaluation of a Quantitative Method for Trace Impurities in Arsenous Acids by Synchrotron Radiation X-ray Fluorescence Spectrometry and Inductively Coupled Plasma-Atomic Emission Spectrometry

Shinichi SUZUKI,* Yasuhiro SUZUKI,* Hikoto OHTA,* Masaaki KASAMATSU,* and Toshio NAKANISHI**

*National Research Institute of Police Science, 6-3-1, Kashiwanoha, Kashiwa-shi, Chiba 277-0882, Japan
**Forensic Science Laboratory, Hyogo Prefecture Police H. Q., 5-4-1, Shimoyamatedori, Chuo-ku, Kobe-shi, Hyogo 650-8510, Japan

Thirteen arsenous acid samples of known origins and refining methods were collected. Each sample was subjected to quantitative analysis of any impurity elements present using synchrotron radiation X-ray fluorescence spectrometry (SR-XRF) and inductively coupled plasma-atomic emission spectrometry (ICP-AES). The trace elements selected were Sn, Sb and Bi for the reasons that they were considered not to be changed by their circumstances and that they showed high sensitivity to SR-XRF. These results obtained by both methods were compared and the correlation between these two methods was determined. The quantification of trace impurities obtained by SR-XRF using As as an internal standard showed good agreement with the results obtained by ICP-AES. The discrimination of refining method became possible by the comparison of these impurities’contents measured with non-destructive SR-XRF using several arsenous acid particles.

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