Analytical Sciences

Extraction Capacity of Diglycolamide Derivatives for Ca(II), Nd(III) and Zr(IV) from Nitric Acid to n-Dodecane Containing a Solvent Modifier

Yuji SASAKI, Zhi-Xuan ZHU, Yumi SUGO, Hideya SUZUKI, and Takaumi KIMURA

Department of Materials Science, Japan Atomic Energy Research Institute, Tokai-mura, Ibaraki 319-1195, Japan

In order to evaluate the extraction property of new extractants, diglycolamide (DGA) compounds, we investigated the maximum extraction of di-, tri-, and tetravalent metal ions using nitric acid and n-dodecane. The limits of metal concentration (LOC) for Ca(II), Nd(III) and Zr(IV) in the organic phase are strongly influenced by HNO₃ and the extractant concentration. For the purpose of enhancing the LOC value, we employed a modifier of the solvent, N,N-dihexyl-octanamide (DHOA) and DGA with a long alkyl chain, and examined the results. It was evident that LOC increased with the DHOA concentration and the length of the alkyl chain attached to the N atom of DGA. The stoichiometric values of LOC(Zr) estimated from the extraction reaction were confirmed by using the extraction condition: tetraoctyl-DGA/1 M DHOA + n-dodecane and 3 M HNO₃.

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