Analytical Sciences

Extractive Spectrophotometric Determination of Cobalt(II) in Synthetic and Pharmaceutical Samples Using Cyanex 923

B. Ramachandra REDDY,  P. RADHIKA, J. Rajesh KUMAR, D. Neela PRIYA, and K. RAJGOPAL

Inorganic Chemistry Division, Indian Institute of Chemical Technology (CSIR), Hyderabad-500 007, India

Cyanex 923 has been proposed as a sensitive analytical reagent for the direct extractive spectrophotometric determination of cobalt(II). Cobalt(II) forms a blue-colored complex with Cyanex 923 in the organic phase. The maximum absorbance of the complex is measured at 635 nm. Beer’ law was obeyed in the range 58.9 - 589.0 µg of cobalt. The molar absorptivitiy and Sandell’ sensitivity of the complex was calculated to be 6.79 × 10² l mol^-1 cm^-1 and 0.088 µg cm^-2, respectively. The nature of the extracted species was found to be Co(SCN)₂⋅2S. An excellent linearity with a correlation coefficient value of 0.999 was obtained for the Co(II)-Cyanex 923 complex. Stability and regeneration of the reagent (Cyanex 923) for reuse is the main advantage of the present method. The method was successfully applied to the determination of cobalt in synthetic mixtures and pharmaceutical samples was found to give values close to the actual ones. Standard alloy samples, such as high-speed tool BCS 484 and 485, have been tested for the determination of cobalt for the purpose of validating the present method. The results of the proposed method are comparable with atomic absorption spectrometry and were found to be in good agreement.

J-STAGE: View this article in J-STAGE