Analytical Sciences

Solvent Extraction of Ni(II) from Sulfate Solutions with LIX 84I: Flow-Sheet for the Separation of Cu(II), Ni(II) and Zn(II)

B. Ramachandra REDDY and D. Neela PRIYA

Inorganic Chemistry Division, Indian Institute of Chemical Technology (CSIR), Hyderabad 500 007, India

This paper reports on solvent-extraction studies of Ni(II) from sulfate solutions with LIX 84I (2-hydroxy-5-nonylacetophenoneoxime) as the extractant. The extraction of metal depends on the equilibrium pH of the aqueous phase and the extractant concentration. The transfer of metal follows a cation exchange-type mechanism: Ni²⁺ + 2HA → NiA₂ + 2H⁺. Extraction varies with the nature of the diluents. Temperature has no effect on the extraction of metal. The extraction behavior of associated metals clearly demonstrates the application of LIX 84I as the extractant for the separation of Cu(II), Ni(II) and Zn(II). Based on the results, a flow sheet of the process was developed.

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