Abstract − Analytical Sciences, 20(12), 1733 (2004).
A Novel Separation and Preconcentration Method for Traces of Manganese, Cobalt, Zinc and Cadmium Using Coagulation of Colloidal Silica
Junichi NAKAJIMA,* Masanori FUJINAMI,** and Koichi OGUMA**
*Quality Materials Science, Graduate School of Science and Technology, Chiba University, 1-33 Yayoi-cho, Inage-ku, Chiba 263-8522, Japan
**Department of Applied Chemistry and Biotechnology, Faculty of Engineering, Chiba University, 1-33 Yayoi-cho, Inage-ku, Chiba 263-8522, Japan
**Department of Applied Chemistry and Biotechnology, Faculty of Engineering, Chiba University, 1-33 Yayoi-cho, Inage-ku, Chiba 263-8522, Japan
A separation and preconcentration method has been developed for traces of heavy metals using coagulation of colloidal silica. An appropriate amount of colloidal silica was added to a sample solution, the pH was adjusted to 11 with tetramethylammonium hydroxide solution and calcium chloride solution was then added to coagulate the silica. The coagulated silica and solution were separated by centrifugation, and the silica was then treated with hydrofluoric and perchloric acids. The residue was taken up in dilute nitric acid and subjected to ICP-AES to determine manganese, cobalt, zinc and cadmium. The proposed method was successfully applied to analysis of river-water.
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