Abstract − Analytical Sciences, 20(12), 1681 (2004).
Conformational Effect of Silica-supported Poly(octadecyl acrylate) on Molecular-Shape Selectivity of Polycyclic Aromatic Hydrocarbons in RP-HPLC
Makoto TAKAFUJI,* Megumi FUKUI,* Hamid R. ANSARIAN,** Mahnaz DERAKHSHAN,* Atsuomi SHUNDO,* and Hirotaka IHARA*,***
*Department of Applied Chemistry & Biochemistry, Kumamoto University, 2-39-1 Kurokami, Kumamoto 860-8555, Japan
**SVB Laboratory, Kumamoto University, 2-39-1 Kurokami, Kumamoto 860-8555, Japan
***Institute for Materials Chemistry & Engineering, Kyushu University, 6-10-1 Hakozaki, Higashi-ku, Fukuoka 812-8581, Japan
**SVB Laboratory, Kumamoto University, 2-39-1 Kurokami, Kumamoto 860-8555, Japan
***Institute for Materials Chemistry & Engineering, Kyushu University, 6-10-1 Hakozaki, Higashi-ku, Fukuoka 812-8581, Japan
Poly(octadecyl acrylate) with a terminal reactive group was synthesized by radical telomerization in various solvents. The polymers were grafted onto porous silica for use in RP-HPLC, and the molecular recognition ability was investigated along with the selectivity for the structural isomers of polycyclic aromatic hydrocarbons. The mechanism of selectivity was also investigated with differential scanning calorimetry and NMR spectroscopic observations.
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