Abstract − Analytical Sciences, 19(9), 1345 (2003).
Crystal Structure of Bis(2-(2-thiazolylazo)-4-methylphenol)cobalt(III)chloride
Lumduan MANGSUP,* Sutatip SIRIPAISARNPIPAT,* and Narongsuk CHAICHIT**
*Laboratory of Crystallography and Gemmology, Department of Chemistry, Faculty of Science, Kasetsart University, Thailand
**Department of Physics, Faculty of Science and Technology, Thammasart University, Thailand
**Department of Physics, Faculty of Science and Technology, Thammasart University, Thailand
The reaction between CoCl2·6H2O and 2-1-(2-thiazolylazo)-p-cresol (TAC) in acetone resulted in six coordinated cobalt(III) complex, [Co(TAC)2]Cl3. Two TAC ligands coordinate with cobalt ion forming four five membered chelate rings. The cobalt ion is octahedrally coordinated by a phenolic oxygen, azo nitrogen and nitrogen in thiazole rings. Three chloride ions are disordered.
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