Analytical Sciences

Simultaneous Determination of Gallium and Indium with 2-(5-Bromo-2-pyridylazo)-5-diethylaminophenol in Cationic Micellar Medium Using Derivative Spectrophotometry

Narinder K. AGNIHOTRI, Sonia RATNANI, Vinay K. SINGH, and Har B. SINGH 

Department of Chemistry, University of Delhi, Delhi 110007, India

A new derivative spectrophotometric method for rapid and selective trace analysis of Ga³⁺ and In³⁺ and for their simultaneous determination using 2-(5-bromo-2-pyridylazo)-5-diethylaminophenol in a cationic micellar medium is reported. Molar absorptivity and Sandell's sensitivity of 1:1 Ga³⁺ and In³⁺ complexes at their lambda_max 553 nm and 558 nm are: 7.22 x 10⁴ l mol^-1 cm^-1 and 5.85 x 10⁴ l mol^-1 cm^-1, and 0.96 ng cm^-2 and 1.96 ng cm^-2, respectively. Linearity is observed in the concentration range 0.023 - 0.700 ug ml^-1 for gallium and 0.076 - 1.52 ug ml^-1 for indium; IUPAC detection limit is 0.012 and 0.035 ng ml^-1, respectively. These metal ions interfere with the determination of each other. However, 0.07 - 0.70 ug ml^-1 Ga³⁺ and 0.115 - 1.150 ug ml^-1 In³⁺ could be determined simultaneously when present together by the derivative method without any prior separation. The proposed procedures have been successfully applied for the individual and simultaneous determination of gallium and indium in synthetic binary mixtures, standard reference materials and environmental samples.

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