Abstract − Analytical Sciences, 19(7), 1085 (2003).
Structural Isomers in a2-(5-Bromo-2-pyridylazo)-5-diethylaminophenolatochloropalladium(II)Crystal
Akira OHASHI, Toshiaki TSUKUDA, andHitoshi WATARAI
Department of Chemistry, Graduate Schoolof Science, Osaka University, Toyonaka, Osaka 560-0043, Japan
Crystal structure of2-(5-bromo-2-pyridylazo)-5-diethylaminophenolatochloropalladium(II) (PdLCl)has been determined by X-ray diffraction. A crystal of PdLCl wasconstructed by two structural isomers of PdLCl molecules, which wereparticularly different in the positions of the carbon atoms at thediethylamino group, having cis-like or trans-like conformation forthe carbon atoms. The molecules of PdLCl in the crystal were warped by asteric hindrance of the diethylamino group.
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