Analytical Sciences

Abstract − Analytical Sciences, 19(6), 835 (2003).

Enrichment Adsorption of a Labile Substance to the Surface of Particular Mineral Particles in River Water as Investigated by SEM-EDX and Dilute-Acid Extraction/ICP-MS
Tomohiro KYOTANI*,**  and Satoshi KOSHIMIZU***
*Bio Nanotec Research Institute Inc. (BNRI), Mitsui & Co., Ltd. Nanotech Park, 2-1, Koyadai, Tsukuba, Ibaraki 305-0074, Japan
**Japan Science and Technology Corporation (JST), 4-1-8, Honmachi, Kawaguchi, Saitama 332-0012, Japan
***Earth Science Division, Yamanashi Institute of Environmental Sciences, 5597-1, Kenmarubi Kamiyoshida, Fujiyoshida, Yamanashi 403-0005, Japan
The selective enrichment behavior of a labile substance, such as hydroxides, to the surface of particular mineral particles in river water was clarified by scanning electron microscopy/energy dispersive X-ray microanalysis (SEM-EDX). Individual particles other than diatom collected on a 0.45 µm filter from the Fuji and Sagami rivers, central Japan, were analyzed by SEM-EDX and classified into seventeen groups according to the chemical composition and shape. Phosphorus, sulfur, chlorine, manganese and copper detected in each particle collected on the 0.45 µm filter could be successfully used as effective indicators of labile substance secondarily formed and adsorbed afresh in river water, because the detection frequencies of such elements are quite low, or negligible, in fresh mineral particles derived from igneous rocks. The labile substance adsorbed on mineral particles collected on the 0.45 µm filter was also evaluated by dilute-acid leaching, followed by inductively coupled plasma mass spectrometry (ICP-MS). Almost all parts of the manganese detected in individual particles were those adsorbed afresh as hydroxides together with iron and aluminum. Also, anionic elements, such as phosphorus, sulfur and chlorine, formed complexes with the hydroxides and/or were incorporated in them. Mg and/or Ca-rich aluminosilicate groups were the most effective adsorbers of such labile species. However, Si-rich and Na-, K- and Na-Ca rich aluminosilicates did not significantly adsorb the labile substance. Consequently, the remarkable selectivity was clarified in the adsorption process of labile substance to individual mineral particles in river water.