Abstract − Analytical Sciences, 19(2), 335 (2003).
Crystal Structure of [2,6-Bis(3,5-dimethyl-N-pyrazolyl)pyridine]-(azido)(chloro)-copper(II)
Raif KURTARAN,*1 Cengiz ARICI,*2 Sefa DURMU,*3 Dinçer ÜLKÜ,*2 and Orhan ATAKOL*4
*1 Department of Chemistry, Faculty of Arts and Sciences, Balikesir University, Balikesir 10100, Turkey
*2 Department of Engineering Physics, Hacettepe University, Beytepe 06532, Ankara, Turkey
*3 Department of Chemistry, Faculty of Education, Abant Izzet Baysal University, Bolu, Turkey
*4 Department of Chemistry, Ankara University, Tandogan 06100, Ankara, Turkey
*2 Department of Engineering Physics, Hacettepe University, Beytepe 06532, Ankara, Turkey
*3 Department of Chemistry, Faculty of Education, Abant Izzet Baysal University, Bolu, Turkey
*4 Department of Chemistry, Ankara University, Tandogan 06100, Ankara, Turkey
In the title compound, the coordination around the Cu atom is a distorted square-pyramid involving three N atoms from the ligand and one N atom from the azido group at the basal plane. The Cl atom is located at the apical position. The Cu atom is 0.32(5)Å above the basal plane. There are three intramolecular and four weak intermolecular hydrogen bonds in the structure. IR spectra confirm the asymmetric N3 stretching vibrations of the terminal azide group.
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